PMID: 12778704Jun 5, 2003Paper

The truly symmetrical doubly-bridging mode of trimethylphosphine in a dinuclear rhodium complex

Chemical Communications : Chem Comm
Thomas PechmannHelmut Werner

Abstract

The dinuclear complex [Rh2I2(mu-CPh2)2(mu-PMe3)] was prepared from the Rh2(acac)2 counterpart and Me3SiI and shown crystallographically to contain the PMe3 ligand in a truly symmetrical bridging position; a new synthetic route to migrate more bulky phosphines such as PPh3 and PiPr3 from a terminal into a bridging site is also described.

Citations

Aug 19, 2007·Angewandte Chemie·Huailin SunQiuchang Wang
Feb 16, 2008·Chemistry : a European Journal·Brigitte NohraRégis Réau
Dec 4, 2008·Dalton Transactions : an International Journal of Inorganic Chemistry·Jeanne Crassous, Régis Réau
Apr 1, 2009·Dalton Transactions : an International Journal of Inorganic Chemistry·Stefan WelschManfred Scheer
Jun 9, 2005·Angewandte Chemie·François LecaRégis Réau
Sep 30, 2010·Angewandte Chemie
May 11, 2011·Chemistry : a European Journal·Sandra SchinzelMartin Kaupp
Nov 2, 2011·Philosophical Transactions of the Royal Society of London. Series B, Biological Sciences·Valerie Curtis
Nov 10, 2006·Chemical Reviews·Thomas Baumgartner, Régis Réau
Mar 23, 2021·Angewandte Chemie·Andrey Y BaranovAlexander V Artem'ev

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