The "Wanderlust" of Me3 Si groups in rare-earth triple-decker complexes: a combined experimental and computational study

Chemical Communications : Chem Comm
Volker LorenzFrank T Edelmann

Abstract

The migration of Me3Si groups ("Wanderlust") in rare-earth triple-decker sandwich complexes of the type Ln2(COT'')3 (COT'' = bis(trimethylsilyl)cyclooctatetraenyl) has been elucidated by a combined experimental and computational study. For the first time, two isomers of a Ln2(COT'')3 triple-decker have been isolated and characterized in the case of Y2(COT'')3.

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Citations

Apr 25, 2020·Chemistry : a European Journal·Dennis A BuschmannReiner Anwander

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Methods Mentioned

BETA
NMR
X-ray

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