Thermally activated isomeric all-hydrocarbon molecular receptors for fullerene separation

Chemical Communications : Chem Comm
Yu-Dong Yang, Han-Yuan Gong

Abstract

A new all-hydrocarbon macrocycle, cyclo[8](1,3-(4,6-dimethyl)benzene) (CDMB-8) has been reported. As prepared, it exists in Cs symmetry and shows no interaction with fullerenes (e.g., C60 or C70). High temperature (573 K) treatment induces thermal conversion of the material to an isomeric conformer with D4d symmetry as a receptor for fullerene separation.

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Citations

Dec 29, 2020·Journal of the American Chemical Society·Yu-Dong YangHan-Yuan Gong
Aug 8, 2021·Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry·Jiří Czernek, Jiří Brus
Sep 16, 2021·Chemical Communications : Chem Comm·Gabrielle A Leith, Natalia B Shustova
Nov 3, 2021·Chemical Communications : Chem Comm·Qiang ShiLeyong Wang

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Methods Mentioned

BETA
X-ray
NMR

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