PMID: 15244643Jul 13, 2004Paper

Thermodynamical scaling of the glass transition dynamics

Physical Review. E, Statistical, Nonlinear, and Soft Matter Physics
R Casalini, C M Roland

Abstract

Classification of glass-forming liquids based on the dramatic change in their properties upon approach to the glassy state is appealing, since this is the most conspicuous and often-studied aspect of the glass transition. Herein, we show that a generalized scaling, log (tau) proportional, variant T-1 V-gamma, where gamma is a material constant, yields superpositioning for ten glass formers, encompassing van der Waals molecules, associated liquids, and polymers. The exponent gamma reflects the degree to which volume governs the temperature and pressure dependence of the relaxation times.

References

Aug 26, 2003·Physical Review. E, Statistical, Nonlinear, and Soft Matter Physics·C DreyfusR M Pick
Oct 4, 2003·Physical Review. E, Statistical, Nonlinear, and Soft Matter Physics·K Mpoukouvalas, G Floudas
Oct 4, 2003·Physical Review. E, Statistical, Nonlinear, and Soft Matter Physics·M PaluchC M Roland

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Citations

Feb 25, 2006·The Journal of Chemical Physics·G FloudasP Papadopoulos
May 3, 2011·The Journal of Chemical Physics·Thomas B SchrøderJeppe C Dyre
Feb 2, 2011·The Journal of Chemical Physics·Sebastian PawlusAndrzej Grzybowski
Jun 28, 2013·The Journal of Chemical Physics·Wen-Sheng Xu, Karl F Freed
Jun 15, 2011·The Journal of Chemical Physics·Ludovic Berthier, Gilles Tarjus
Sep 8, 2011·The Journal of Chemical Physics·Zane ShiPaul Ginart
Jun 21, 2012·The Journal of Chemical Physics·A Swiety-PospiechM Paluch
Jun 16, 2012·The Journal of Chemical Physics·Enriqueta R LópezKenneth R Harris
Sep 21, 2013·The Journal of Chemical Physics·Lisa Anita RoedKristine Niss
Aug 7, 2009·The Journal of Chemical Physics·Gustavo Ariel SchwartzJuan Colmenero
Mar 1, 2012·The Journal of Chemical Physics·Trond S IngebrigtsenJeppe C Dyre
Dec 23, 2009·The Journal of Chemical Physics·Nicoletta GnanJeppe C Dyre
May 5, 2007·The Journal of Chemical Physics·A Drozd-RzoskaC M Roland
Nov 26, 2008·The Journal of Chemical Physics·Kristine NissChristiane Alba-Simionesco
Sep 11, 2007·The Journal of Chemical Physics·Alexander PuzenkoMarian Paluch
Nov 4, 2011·The Journal of Chemical Physics·A C BrańkaG Rickayzen
Jan 25, 2013·The Journal of Chemical Physics·D M Heyes, A C Brańka
Mar 18, 2006·The Journal of Chemical Physics·H KriegsA Patkowski
Jul 19, 2012·The Journal of Chemical Physics·Murari SinghCharusita Chakravarty
Oct 4, 2006·The Journal of Chemical Physics·C M RolandR Casalini
Apr 29, 2010·The Journal of Chemical Physics·Anthony N Papathanassiou, Ilias Sakellis
Jan 15, 2009·The Journal of Chemical Physics·D Coslovich, C M Roland
Dec 16, 2011·The Journal of Chemical Physics·R CasaliniC M Roland
Apr 19, 2011·The Journal of Chemical Physics·Enriqueta R LópezKenneth R Harris
Dec 3, 2008·The Journal of Chemical Physics·Nicholas P BaileyJeppe C Dyre
Aug 25, 2011·The Journal of Chemical Physics·Jiaxi Guo, Sindee L Simon
Jul 26, 2006·The Journal of Chemical Physics·R CasaliniC M Roland
Jun 24, 2010·The Journal of Chemical Physics·D Coslovich, C M Roland
Apr 26, 2005·The Journal of Chemical Physics·C M Roland, R Casalini
May 3, 2014·The Journal of Chemical Physics·Saurav Prasad, Charusita Chakravarty
Aug 12, 2014·The Journal of Chemical Physics·Arno A VeldhorstThomas B Schrøder
Jan 17, 2016·The Journal of Chemical Physics·R Casalini, C M Roland
Nov 23, 2015·The Journal of Chemical Physics·Arno A VeldhorstThomas B Schrøder

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