Three novel interpenetrating diamondoid networks from self-assembly of 1,12-dodecanedinitrile with silver(I) salts

Chemistry : a European Journal
Lucia CarlucciSilvia Rizzato

Abstract

The self-assembly of 1,12-dodecanedinitrile (ddn) with various silver salts (NO(3)(-), PF(6)(-), AsF(6)(-), ClO(4)(-)) afforded new polymeric coordination networks with the general formula [Ag(ddn)(2)]X. All these species contain interpenetrating diamondoid nets showing interesting features: with X=NO(3)(-) the cationic [Ag(ddn)(2)](+) network exhibits the highest interpenetration (tenfold) ever found within diamondoid nets exclusively based on coordinative bonds. When X=PF(6)(-) or AsF(6)(-) an eightfold diamondoid network is obtained that shows an unusual [4+4] mode of interpenetration, instead of the "normal" set of eight nets equally translated along a principal axis of the adamantanoid cages. The polymeric species that forms with X=ClO(4)(-) is a fourfold interpenetrating diamondoid network; the lower degree of interpenetration in this case is related to the conformation assumed by the flexible ddn ligands.

Citations

Sep 15, 2005·Chemical Communications : Chem Comm·Katharina M FrommAdeline Y Robin
Apr 5, 2007·Chemistry : a European Journal·Pierangelo MetrangoloGiuseppe Resnati
Nov 14, 2012·Dalton Transactions : an International Journal of Inorganic Chemistry·Inès ChevrierKatharina M Fromm
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Nov 15, 2007·Chemistry : a European Journal·Hong ZhaoPhilip Wai Hong Chan
Apr 3, 2008·Dalton Transactions : an International Journal of Inorganic Chemistry·Ai-Ling ChengEn-Qing Gao
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