Three-state near-infrared electrochromism at the molecular scale

Journal of the American Chemical Society
Bin-Bin CuiJiannian Yao

Abstract

Self-assembled monolayer films of a cyclometalated ruthenium complex with a redox-active amine substituent and three carboxylic acid groups have been prepared on ITO electrode surfaces. The obtained thin films show three-state electrochromic switching with low electrochemical potential inputs and high near-infrared absorbance outputs. Thanks to the long retention time of each oxidation states, these films have been used to demonstrate surface-confined flip-flop memory functions with high ON/OFF ratios at the molecular scale.

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Citations

Oct 27, 2015·ACS Applied Materials & Interfaces·Silja AbrahamJoshy Joseph
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