TiO2 Nanotubes with Pt and Pd Nanoparticles as Catalysts for Electro-Oxidation of Formic Acid

Materials
Marcin PisarekMaria Janik-Czachor

Abstract

In the present work, the magnetron sputtering technique was used to prepare new catalysts of formic acid electrooxidation based on TiO2 nanotubes decorated with Pt (platinum), Pd (palladium) or Pd + Pt nanoparticles. TiO2 nanotubes (TiO2 NTs) with strictly defined geometry were produced by anodization of Ti foil and Ti mesh in a mixture of glycerol and water with ammonium fluoride electrolyte. The above mentioned catalytically active metal nanoparticles (NPs) were located mainly on the top of the TiO2 NTs, forming 'rings' and agglomerates. A part of metal nanoparticles decorated also TiO2 NTs walls, thus providing sufficient electronic conductivity for electron transportation between the metal nanoparticle rings and Ti current collector. The electrocatalytic activity of the TiO2 NTs/Ti foil, decorated by Pt, Pd and/or Pd + Pt NPs was investigated by cyclic voltammetry (CV) and new Pd/TiO2 NTs/Ti mesh catalyst was additionally tested in a direct formic acid fuel cell (DFAFC). The results so obtained were compared with commercial catalyst-Pd/Vulcan. CV tests have shown for carbon supported catalysts, that the activity of TiO2 NTs decorated with Pd was considerably higher than that one decorated with Pt. Moreover, for TiO2 NTs sup...Continue Reading

References

Oct 16, 2009·Physical Chemistry Chemical Physics : PCCP·Sunghyun UhmJaeyoung Lee
Jan 28, 2011·ACS Applied Materials & Interfaces·Robert E RettewFaisal M Alamgir
Aug 15, 2014·Chemical Reviews·Kiyoung LeePatrik Schmuki

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Citations

Jan 21, 2021·Materials·Janaina Soares SantosFrancisco Trivinho-Strixino
Aug 28, 2021·Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry·Scott J FolkmanJosé Ramón Galán-Mascarós

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thermal treatment
quartz microbalance
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