Topology analysis and nonlinear-optical-active properties of luminescent metal-organic framework materials based on zinc/lead isophthalates

Inorganic Chemistry
Lei ZhangYuan-Gen Yao

Abstract

Two 3D Zn(II) and Pb(II) isophthalates, [Zn(ip)]n (1) and [Pb4(mu4-O)(ip)3(H2O)]n (2) (H2ip = isophthalic acid), have been prepared under hydro(solvo)thermal conditions and characterized by single-crystal X-ray diffraction. The two complexes crystallize in different space groups (P4(3)2(1)2 for 1 and P2(1)/c for 2) and have different bridging modes of the ip ligand. The 3D framework of 1 is constructed by the interconnection of ZnO4 polyhedra via ip ligands, which represents a chiral net with PtS-type topology. In contrast, complex 2 is formed by the combination of Pb4O-cluster secondary building units and has a novel (3.4.5)(3(2).4(5).5(6).6(7).7(2)) topology, which is the first ever example of a (3,7)-connected net. Complex 1 displays a second harmonic generation efficiency of about 1.5 times that of KH2PO4. Optical properties and thermal stabilities of the two complexes have been studied. Additionally, the calculations of band structure and density of states of 1 have also been performed with the density functional theory method.

References

Oct 15, 1987·Physical Review. B, Condensed Matter·R W GodbyL J Sham
Jun 16, 2001·Acta Crystallographica. Section C, Crystal Structure Communications·T J Otto, K A Wheeler
Aug 2, 2001·Journal of the American Chemical Society·P A MaggardK R Poeppelmeier
Dec 26, 2001·Chemical Reviews·S LeiningerP J Stang
Jul 18, 2002·Accounts of Chemical Research·Owen R Evans, Wenbin Lin
Mar 17, 2004·Angewandte Chemie·C N R RaoR Vaidhyanathan
Apr 29, 2004·Angewandte Chemie·Susumu KitagawaShin-ichiro Noro
Mar 16, 2005·Accounts of Chemical Research·Nathan W OckwigOmar M Yaghi
Apr 20, 2005·Accounts of Chemical Research·Gérard FéreyFranck Millange
Apr 27, 2005·Dalton Transactions : an International Journal of Inorganic Chemistry·Qiong YeRen-Gen Xiong
May 26, 2005·Journal of the American Chemical Society·Xian-Ming ZhangHai-Shun Wu
Sep 21, 2005·Accounts of Chemical Research·Olivier Maury, Hubert Le Bozec
Sep 30, 2005·Chemical Communications : Chem Comm·Xin-Long WangStuart R Batten
Sep 11, 2007·Dalton Transactions : an International Journal of Inorganic Chemistry·Partha MahataSrinivasan Natarajan
Oct 31, 2007·Journal of the American Chemical Society·Jian ZhangXianhui Bu
Nov 15, 2007·Journal of the American Chemical Society·Jonathan L BelofBrian Space
Jun 19, 1998·Angewandte Chemie·Stuart R Batten, Richard Robson
Jul 2, 2001·Angewandte Chemie·De-Liang LongMartin Schröder

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Citations

Sep 21, 2012·Acta Crystallographica. Section B, Structural Science·Kate DaviesClive L Oliver
Jan 6, 2012·Acta Crystallographica. Section E, Structure Reports Online·Qin ZhongXue-Ting Zhang
Oct 11, 2014·Chemical Communications : Chem Comm·Jane V KnichalChick C Wilson
Apr 1, 2009·Dalton Transactions : an International Journal of Inorganic Chemistry·Zhou ZhaoShourong Zhu
Apr 8, 2010·Dalton Transactions : an International Journal of Inorganic Chemistry·Hazel FentonMichael D Ward
Oct 21, 2010·Chemistry : a European Journal·Ilich A IbarraMartin Schröder
Nov 17, 2012·Dalton Transactions : an International Journal of Inorganic Chemistry·Xin ZhangYuan-Gen Yao
Feb 24, 2012·Dalton Transactions : an International Journal of Inorganic Chemistry·Qipu LinPingyun Feng
Nov 30, 2012·Dalton Transactions : an International Journal of Inorganic Chemistry·Han-Rui TianJian-Wen Cheng
Jul 6, 2014·Acta Crystallographica. Section C, Structural Chemistry·Shao-Min ChengWen-Long Liu
Jan 28, 2010·Dalton Transactions : an International Journal of Inorganic Chemistry·Seong HuhSeongsoon Park
Oct 22, 2010·Inorganic Chemistry·Catherine M MauckCatherine M Oertel
Jan 30, 2018·Inorganic Chemistry·Miroslav AlmášiJiří Čejka

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