Total synthesis of schilancitrilactones b and C

Angewandte Chemie
Liang WangPingping Tang

Abstract

The first total syntheses of schilancitrilactones B and C have been accomplished in 17 steps (longest linear sequence) from commercially available materials. Key steps include an intramolecular radical cyclization to provide the seven-membered ring, late-stage iodination, and an intermolecular radical addition reaction to complete the total synthesis.

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Citations

Sep 24, 2015·Journal of the American Chemical Society·Zhaohong LuAng Li
Jul 17, 2015·Journal of the American Chemical Society·Lin YouZhen Yang
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