Towards Macroscopic Crystalline 2D Polymers

Angewandte Chemie
Xinliang Feng, A Dieter Schlüter

Abstract

Periodic and nanoporous monolayer polymers, the structures of which can be viewed as molecular fishing nets, have been classified as 2D polymers. They have been previously synthesized under mild photoirradiation conditions in the interior of layered single crystals of well-designed monomers, followed by a liquid-phase exfoliation. While these mild conditions allow for full structure control, the size of 2D polymers obtained cannot exceed that of the crystals from which they are prepared. In this Review, we discuss different concepts currently pursued to prepare macroscopically sized 2D polymers, focusing on syntheses at the air-water and liquid-liquid interfaces. While these interfaces are larger reaction loci than single crystals, sheet-like polymers obtained at them pose complex and time-consuming analytical challenges. Some of these challenges are concretely discussed and indicators are provided for identifying the promising cases, enabling to concentrate on them in the future research. Additionally, this Review discusses three representative examples of 2D polymers to provide a state-of-the-art picture of this emerging field of polymer and materials science. Finally, we sketch the range of applications, such as nanomembrane...Continue Reading

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Citations

Apr 11, 2019·Electrophoresis·Jian ZhangXu Hou
Feb 20, 2020·Nanoscale·Honglei WangZhikun Zheng
Apr 9, 2020·Nanoscale·Zian TangAndrey Turchanin
Feb 25, 2020·Angewandte Chemie·Shutao WangJun-Bing Fan
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Jan 30, 2020·Advanced Science·Shameel Thurakkal, Xiaoyan Zhang
Jan 13, 2021·Nanoscale·Xianghui Zhang, André Beyer
Apr 7, 2021·Langmuir : the ACS Journal of Surfaces and Colloids·Ming HanHong-Guo Liu
Jul 8, 2021·Advanced Functional Materials·Ehsan MohammadifarMohsen Adeli
Jun 25, 2021·Chemical Science·Andreas SchneemannStefan Kaskel
Feb 6, 2020·ACS Nano·Nerea BilbaoSteven De Feyter
Jul 31, 2019·ACS Applied Materials & Interfaces·Christof NeumannAndrey Turchanin
Sep 12, 2019·Journal of the American Chemical Society·Gangfeng ChenXiaoyu Li

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