Transient two-dimensional infrared spectroscopy: exploring the polarization dependence

The Journal of Chemical Physics
Jens BredenbeckPeter Hamm

Abstract

We present a general expression for the polarization dependence of transient two-dimensional IR spectroscopy (T2D-IR), a technique designed to measure 2D-IR spectra of transient species. T2D-IR is a UV pump narrowband-IR-pump broadband-IR-probe experiment of fifth order in the laser field which involves up to three different transition dipole moments. The UV pulse adds an additional degree of freedom in polarization as compared to 2D-IR spectroscopy and increases the versatility of signal manipulation and the potential structural information content of the signals. The polarization conditions leading to a maximum of structural information are discussed. Important special cases of polarization conditions are formulated. The application of polarization selectivity is demonstrated for different types of T2D-IR experiments on photo triggered metal-to-ligand charge transfer in the model system [Re(CO)(3)(dmbpy)Cl].

References

Mar 3, 1999·Proceedings of the National Academy of Sciences of the United States of America·P HammR M Hochstrasser
Sep 13, 2001·Proceedings of the National Academy of Sciences of the United States of America·S WoutersenP Hamm
Sep 20, 2001·Proceedings of the National Academy of Sciences of the United States of America·M T ZanniR M Hochstrasser
Jan 12, 2002·Current Opinion in Structural Biology·M T Zanni, R M Hochstrasser
Feb 19, 2002·Chemical Reviews·Jon R. Schoonover, Geoffrey F. Strouse
Aug 9, 2002·Journal of the American Chemical Society·Kenneth Kam-Wing LoDominic Chun-Ming Ng
Dec 18, 2002·Physical Review Letters·N DemirdövenA Tokmakoff
Dec 11, 2007·Optics Letters·P HammJ Stenger

❮ Previous
Next ❯

Citations

Mar 29, 2008·Science·James F CahoonCharles B Harris
Nov 9, 2007·Annual Review of Physical Chemistry·Peter HammJens Bredenbeck
Jan 31, 2007·Proceedings of the National Academy of Sciences of the United States of America·Jens BredenbeckPeter Hamm
Mar 10, 2015·Annual Review of Physical Chemistry·Natalia I Rubtsova, Igor V Rubtsov
Oct 27, 2016·The Journal of Chemical Physics·Joel D LegerIgor V Rubtsov
Oct 27, 2017·Topics in Current Chemistry·Jan Philip Kraack
Dec 22, 2017·Nature Communications·Matthijs R PanmanSander Woutersen
Jul 7, 2007·Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry·Jens BredenbeckPeter Hamm
Aug 31, 2019·Journal of Physics. Condensed Matter : an Institute of Physics Journal·Yaron Paz
May 14, 2010·New Journal of Physics·David B StrasfeldMartin T Zanni
Jul 16, 2014·Dalton Transactions : an International Journal of Inorganic Chemistry·N T Hunt
Dec 12, 2012·Physical Chemistry Chemical Physics : PCCP·Matthijs R PanmanSander Woutersen
Jul 21, 2015·Optics Express·Biplab Dutta, Jan Helbing
Jun 24, 2008·The Journal of Physical Chemistry. B·Valentina CervettoJan Helbing
Jun 16, 2009·The Journal of Physical Chemistry. a·Carlos R BaizKevin J Kubarych
Apr 11, 2009·The Journal of Physical Chemistry. B·Esben Ravn Andresen, Peter Hamm
May 15, 2010·The Journal of Physical Chemistry. a·Amal El NahhasMajed Chergui
Jul 10, 2021·The Journal of Chemical Physics·James D GaynorMunira Khalil
Sep 10, 2010·The Journal of Physical Chemistry. a·Kristin A BrineyF Fleming Crim
Oct 23, 2013·The Journal of Physical Chemistry. a·Maxim F Gelin, Wolfgang Domcke
Nov 29, 2017·Journal of the American Chemical Society·Daniela Kern-MichlerJens Bredenbeck
Jul 25, 2018·The Journal of Physical Chemistry. B·David G HogleMatthew J Tucker
Jan 10, 2018·The Journal of Physical Chemistry. B·Nilangshu Mandal, Ayan Datta
Nov 28, 2012·The Journal of Physical Chemistry. a·Daniel B TurnerDarin J Ulness
May 31, 2012·The Journal of Physical Chemistry. a·Michael S LynchMunira Khalil
Apr 4, 2015·Accounts of Chemical Research·Laura M KieferKevin J Kubarych
Sep 10, 2014·The Journal of Physical Chemistry. B·Milan DelorJulia A Weinstein
Mar 20, 2015·Accounts of Chemical Research·Milan DelorJulia A Weinstein

❮ Previous
Next ❯

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.

Related Papers

Proceedings of the National Academy of Sciences of the United States of America
Martin T ZanniR M Hochstrasser
Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry
Jens BredenbeckPeter Hamm
Journal of the American Chemical Society
Chantelle L AnfusoTianquan Lian
© 2021 Meta ULC. All rights reserved