Transition metal-catalyzed ring-opening polymerization (ROP) of strained, silicon-bridged bis(benzene)chromium complexes

Dalton Transactions : an International Journal of Inorganic Chemistry
Andrea Berenbaum, Ian Manners

Abstract

Silicon-bridged bis(benzene)chromium complexes (sila[1]chromarenophanes) undergo facile transition metal-catalyzed ROP at ambient temperature in the presence of Karstedt's catalyst to yield polychromarenylsilanes, the first homopolymers with main chains of Cr(arene)(2) and organosilane units.

Citations

Mar 26, 2005·Chemical Communications : Chem Comm·Matthias TammEberhardt Herdtweck
Sep 4, 2010·Journal of the American Chemical Society·Inmaculada MatasIan Manners
May 16, 2006·Nature Materials·Makoto TanabeIan Manners
May 19, 2018·Chemical Society Reviews·Qingchen DongWai-Yeung Wong
Jun 26, 2007·Angewandte Chemie·Vasilios Bellas, Matthias Rehahn
Apr 9, 2008·Angewandte Chemie·Holger BraunschweigGeorge R Whittell
Jun 16, 2010·Dalton Transactions : an International Journal of Inorganic Chemistry·Robin A Krüger, Thomas Baumgartner
Jan 30, 2014·Macromolecular Rapid Communications·Alaa S Abd-El-AzizNola Etkin
Nov 28, 2012·Chemistry : a European Journal·Holger BraunschweigKrzysztof Radacki
Jun 26, 2015·Chemistry : a European Journal·Holger BraunschweigIvo Krummenacher

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