Transmetallation from CCC-NHC pincer Zr complexes in the synthesis of air-stable CCC-NHC pincer Co(iii) complexes and initial hydroboration trials

Dalton Transactions : an International Journal of Inorganic Chemistry
Sean W ReillyHenry U Valle

Abstract

Development of CCC-NHC pincer Co complexes via transmetalation from Zr is reported. Formation of these air-stable Co(iii) complexes was achieved through use of a CoCl2 or Co(acac)3in situ or with a discrete CCC-NHC pincer Zr transmetallating agent. Preliminary activity in the hydroboration of styrene is reported. This facile methodology will further the development of CCC-NHC pincer first-row transition metal complexes.

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Apr 13, 2017·Chemical Communications : Chem Comm·Jingying PengStephen P Thomas
May 16, 2017·Chemical Communications : Chem Comm·Hagit Ben-DaatRyan J Trovitch
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