Trifluoromethylfluorosulfonylation of Unactivated Alkenes Using Readily Available Ag(O2 CCF2 SO2 F) and N-Fluorobenzenesulfonimide

Angewandte Chemie
Yongan LiuChao Liu

Abstract

Presented is a novel intermolecular radical trifluoromethylfluorosulfonylation of unactivated alkenes under mild reaction conditions with good functional-group tolerance in the most atom-economic manner by using readily available Ag(O2 CCF2 SO2 F) and N-fluorobenzenesulfonimide (NFSI). Both the trifluoromethyl and sulfonyl groups in the products originate from Ag(O2 CCF2 SO2 F).

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Citations

Jun 14, 2018·Chemistry, an Asian Journal·Ji-Shu ZhangLi-Biao Han
May 25, 2021·Chemical Society Reviews·Pan XiaoSamuel Couve-Bonnaire
Aug 6, 2021·Chemical Science·Tao ZhongJiang Weng
Oct 5, 2019·The Journal of Organic Chemistry·Cong XuMang Wang
Dec 28, 2021·Angewandte Chemie·Nils Lennart FryeArmido Studer

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