Trifluoromethylselenolation of Aryldiazonium Salts: A mild and Convenient Copper-Catalyzed Procedure for the Introduction of the SeCF3 Group

Chemistry : a European Journal
Pavlo Nikolaienko, Magnus Rueping

Abstract

The straightforward introduction of the trifluoromethylseleno group into aromatic and heteroaromatic compounds is accomplished by the utilization of readily available aryldiazonium tetrafluoroborates, potassium selenocyanate, and Ruppert-Prakash reagent. The reaction tolerates a wide range of aromatic and heteroaromatic diazonium salts and is also amenable to the synthesis of pentafluoroethyl selenoethers. Furthermore, the methodology can be applied directly starting from anilines.

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Citations

Jul 6, 2016·Chemistry : a European Journal·Christian MatheisLukas J Goossen
Nov 3, 2016·Chemistry : a European Journal·Wei WuZhiqiang Weng
May 24, 2017·Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry·Clément GhiazzaThierry Billard
Oct 27, 2017·Chemistry : a European Journal·Anis TliliThierry Billard
Jul 10, 2018·Angewandte Chemie·Clément GhiazzaAnis Tlili
Jan 15, 2019·Chemical Communications : Chem Comm·Xin-Lei ChenJi-Chang Xiao
Apr 8, 2020·Beilstein Journal of Organic Chemistry·Clément Ghiazza, Anis Tlili
Nov 5, 2020·Organic & Biomolecular Chemistry·Zhen YangYu Wei
Oct 13, 2020·Chemistry : a European Journal·Xue ZhangHua-Yue Wu
Sep 20, 2017·Organic Letters·Yong Guan, Steven D Townsend
Aug 22, 2021·Molecular Diversity·Rabia AkhtarKulsoom Ghulam Ali
Dec 14, 2017·Organic Letters·Quentin GlenadelThierry Billard

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