Trinorcassane and cassane diterpenoids from the seeds of Caesalpinia minax

Fitoterapia
Yong ZhengLi-Jiang Xuan

Abstract

An unprecedented trinorcassane diterpenoid and a cassane furanoditerpenoid were isolated from the seeds of Caesalpinia minax. It is the first example of dicylic cassane-type trinorditerpenoid, which is different from reported 16- or 17-norcassane diterpenoids. The structure of the compounds was elucidated on the basis of 1D and 2D NMR analysis. Biosynthesis pathways are postulated, and this pathway was supported by semi-synthesis.

References

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Jun 29, 2013·Journal of Natural Products·Guoxu MaXudong Xu
Dec 7, 2013·Journal of Natural Products·Yong ZhengLi-Jiang Xuan

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