Trinuclear scandium methylidyne complexes stabilized by pentamethylcyclopentadienyl ligands.

Chemical Communications : Chem Comm
Peng DengJianhua Cheng

Abstract

The first examples of scandium methylidyne complexes [(Cp*)Sc(μ2-X)]3(μ3-CH) (Cp* = C5Me5; X = Br, Me, OMe), free of Lewis acids, can be achieved in high yields from [(Cp*)ScMe2]2 through a facile route. The chemical and geometrical flexibility to incorporate organic substrates indicates a rich chemistry of complex [(Cp*)Sc(μ2-OMe)]3(μ3-CH).

References

Oct 9, 2003·Angewandte Chemie·Richard R Schrock, Amir H Hoveyda
Aug 11, 2004·Dalton Transactions : an International Journal of Inorganic Chemistry·Garth R Giesbrecht, John C Gordon
Oct 18, 2005·Chemical Communications : Chem Comm·Thibault CantatPascal Le Floch
Jul 20, 2006·Journal of the American Chemical Society·H Martin DietrichReiner Anwander
Jan 23, 2008·Chemical Communications : Chem Comm·Melanie ZimmermannReiner Anwander
Sep 13, 2008·Chemistry : a European Journal·Laura C H GerberReiner Anwander
Oct 14, 2008·Journal of the American Chemical Society·Jennifer ScottDaniel J Mindiola
Oct 31, 2008·Angewandte Chemie·Rannveig LitlabøReiner Anwander
Oct 8, 2009·Dalton Transactions : an International Journal of Inorganic Chemistry·Jennifer Scott, Daniel J Mindiola
Mar 2, 2010·Angewandte Chemie·Daniel BojerNorbert W Mitzel
Jun 25, 2010·Chemical Communications : Chem Comm·Melanie ZimmermannReiner Anwander
Sep 4, 2010·Journal of the American Chemical Society·Marie FustierNicolas Mézailles
Dec 17, 2010·Nature Chemistry·Daniel J Mindiola, Jennifer Scott
Feb 16, 2011·Chemical Society Reviews·Stephen T LiddleAshley J Wooles
Mar 31, 2011·Journal of the American Chemical Society·Wen-Xiong ZhangZhaomin Hou
Jan 8, 2014·Angewandte Chemie·Jochen Kratsch, Peter W Roesky
Oct 7, 2014·Chemistry : a European Journal·Shihui LiDongmei Cui
Sep 30, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Dorothea SchädleReiner Anwander
Dec 1, 2015·Chemistry : a European Journal·Chen WangYaofeng Chen
Mar 15, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Jianquan HongLixin Zhang
Jan 10, 2017·Journal of the American Chemical Society·Weiqing MaoYaofeng Chen
Nov 28, 2017·Journal of the American Chemical Society·Weiqing MaoYaofeng Chen
May 2, 2018·Chemical Society Reviews·O M OgbaR H Grubbs
Jun 15, 2019·Chemistry : a European Journal·Weiqing MaoYaofeng Chen
Aug 1, 2019·Journal of the American Chemical Society·Damir BarisicReiner Anwander
Oct 18, 2019·Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry·Christoph O HollfelderReiner Anwander
Apr 22, 2020·Journal of the American Chemical Society·Pavel ZatsepinDaniel J Mindiola

❮ Previous
Next ❯

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.

Related Papers

Journal of Environmental Science and Health. Part A, Toxic/hazardous Substances & Environmental Engineering
James H WynneSteven Stevenson
Physical Review. B, Condensed Matter
M SigristM Piacentini
© 2021 Meta ULC. All rights reserved