Tri(o-tolyl)phosphine for highly efficient Suzuki coupling of propargylic carbonates with boronic acids

Chemical Communications : Chem Comm
Junzhe XiaoShengming Ma

Abstract

A highly efficient catalytic system consisting of Pd2(dba)3·CHCl3 and tri(o-tolyl)phosphine has been identified for the coupling of propargylic carbonates with different types of organo boronic acids at room temperature. Excellent central-to-axial chirality transfer was also demonstrated.

References

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Citations

Sep 29, 2020·Chemical Communications : Chem Comm·Zhao-Zhao ZhouYong-Min Liang
Jul 25, 2020·The Journal of Organic Chemistry·Calvin Q O'Broin, Patrick J Guiry
Nov 21, 2019·Journal of the American Chemical Society·Chenghao ZhuJunliang Zhang
Dec 16, 2021·Organic & Biomolecular Chemistry·Aline MakhloutahPiétrick Hudhomme

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Methods Mentioned

BETA
NMR

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