Tunable intramolecular multicenter H-bonding interactions in first-row metal complexes bearing bidentate redox-active ligands.

Journal of Coordination Chemistry
Khashayar RajabimoghadamIsaac Garcia-Bosch

Abstract

In this research article, we report the synthesis and structural characterization of a family of first-row metal complexes bearing redox-active ligands with tunable H-bonding donors. We observed that these coordination complexes can adopt three different geometries and that they are stabilized by intramolecular multicenter H-bonding interactions, which are systematically modified by changing the metal ion (Co, Ni, Cu, Zn), the ligand scaffold (variations in the diamine and ureanyl substituents used) and the solvent of crystallization.

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Nov 8, 2018·Journal of the American Chemical Society·Khashayar RajabimoghadamIsaac Garcia-Bosch

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Citations

Jun 13, 2020·Journal of the American Chemical Society·Tong WuIsaac Garcia-Bosch

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Methods Mentioned

BETA
X-ray
NMR

Software Mentioned

Scattegram

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