Tunable Luminescent Lanthanide Supramolecular Assembly Based on Photoreaction of Anthracene

Journal of the American Chemical Society
Yan ZhouYu Liu

Abstract

Lanthanide luminescence materials generally show great superiority in light-emitting materials, gaining increasingly exploration in the design of advanced functional materials. Herein, we prepared a supramolecular assembly via the coordination of a host molecule (1) and dilanthanide metal. Compound 1 possesses a 9,10-diphenylanthracene (ant) core with photosensitivity and terminal terpyridine (tpy), containing two-arm dibenzo-24-crown-8. The assembly could exhibit excellent lanthanide luminescence after undergoing a photoreaction from anthracene unit in 1. Significantly, the luminescence of the assembly could be reversibly switched on and off through a regulable photoreaction upon light irradiation or heating. The multiple functional behavior combined with the ease of assembly reveals that this photo/thermo-controlled lanthanide luminescence supramolecular polymer design method offers a convenient pathway for future engineering of multi-stimuli-responsive materials.

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Citations

Apr 16, 2019·Chemical Communications : Chem Comm·Si-Jia RaoToshikazu Takata
Nov 20, 2019·ChemistryOpen·Yan Zhang, Mihail Barboiu
Dec 7, 2019·Chemical Communications : Chem Comm·Shuai QiuWei Tian
Feb 18, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Binbin ZhangHong Wang
Sep 6, 2020·International Journal of Molecular Sciences·Gengqi LiuYumiao Zhang
Jan 15, 2020·Chemical Science·Cédric MonginBrigitte Bibal
Aug 20, 2021·Journal of the American Chemical Society·Hua-Jiang YuYu Liu
Jan 16, 2020·Journal of the American Chemical Society·Yan-Qin HePeter J Stang
Nov 26, 2020·The Journal of Organic Chemistry·Sourav K Santra, Alex M Szpilman
Feb 23, 2019·Inorganic Chemistry·Frankie D WhiteThomas E Albrecht-Schmitt
Oct 15, 2021·Chemical Communications : Chem Comm·Wei-Lei ZhouYu Liu
Dec 7, 2021·ACS Applied Materials & Interfaces·Ying WuYu Liu
Dec 10, 2021·Macromolecular Rapid Communications·Zhaozhao DuanWei Tian

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