Tuning coordination chemistry through the second sphere in designed metallocoiled coils

Chemical Communications : Chem Comm
Louise N SlopeAnna F A Peacock

Abstract

The metal hydration state within a designed coiled coil can be progressively tuned across the full integer range (3 → 0 aqua ligands), by careful choice of a second sphere terminal residue, including the lesser used Trp. Potential implications include a four-fold change in MRI relaxivity when applied to lanthanide coiled coils.

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Citations

Jun 8, 2021·Chemical Science·Antoine MeunierIvan Huc
Jun 22, 2021·Chemical Communications : Chem Comm·Alexandra M Webster, Anna F A Peacock
May 15, 2020·Journal of the American Chemical Society·Karine MazmanianCarmay Lim

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