Tuning the Metal/Chalcogen Composition in Copper(I)-Chalcogenide Clusters with Cyclic (Alkyl)(amino)carbene Ligands

Inorganic Chemistry
Alexander M PolgarJohn F Corrigan

Abstract

A series of phosphorescent homo- and heterometallic copper(I)-chalcogenide clusters stabilized by cyclic (alkyl)(amino)carbene ligands [Cu4M4(μ3-E)4(CAACCy)4] (M = Cu, Ag, Au; E = S, Se) has been synthesized by the reaction of the new copper(I) trimethylsilylchalcogenolate compounds [(CAACCy)CuESiMe3] with ligand-supported group 11 acetates. The clusters are emissive at 77 K in solution and the solid state, with emission colors that depend on the metal/chalcogen composition. Electronic structure calculations point to a common 3[(M++E2-)LCT] emissive state for the series.

References

May 8, 1997·Chemical Reviews·Pekka Pyykkö
Feb 19, 2002·Chemical Reviews·Peter C. FordJames Bourassa
Sep 21, 2002·Chemical Communications : Chem Comm·J LuoB Z Tang
Aug 5, 2004·Journal of the American Chemical Society·Quan-Ming WangRichard Eisenberg
Sep 30, 2006·Chemistry : a European Journal·Olga CrespoM Dolores Villacampa
Oct 24, 2006·Inorganic Chemistry·Iliana MedinaMark J Fink
Mar 14, 2007·Inorganic Chemistry·Aneta Borecki, John F Corrigan
Jan 29, 2010·Chemical Communications : Chem Comm·Hervé Clavier, Steven P Nolan
Nov 9, 2010·The Journal of Chemical Physics·Florian Weigend, Alexander Baldes
Feb 4, 2012·Dalton Transactions : an International Journal of Inorganic Chemistry·Andreas EichhöferCheng-Yong Su
Aug 25, 2012·Chemical Society Reviews·Olaf FuhrDieter Fenske
Mar 8, 2014·Chemical Society Reviews·Renso Visbal, M Concepción Gimeno
Aug 8, 2014·Chemical Communications : Chem Comm·Xiao-Xun YangAndreas Eichhöfer
Dec 18, 2014·Accounts of Chemical Research·Michèle Soleilhavoup, Guy Bertrand
Dec 30, 2014·Acta Crystallographica. Section A, Foundations and Advances·George M Sheldrick
Jan 9, 2015·Acta Crystallographica. Section C, Structural Chemistry·George M Sheldrick
Apr 18, 2015·Chemical Communications : Chem Comm·Mahmood Azizpoor FardJohn F Corrigan
Jul 15, 2015·Chemical Reviews·Vivian Wing-Wah YamSammual Yu-Lut Leung
Feb 13, 2016·Chemistry : a European Journal·Mahmood Azizpoor FardJohn F Corrigan
Apr 19, 2016·Chemical Communications : Chem Comm·Alexander S RomanovManfred Bochmann
May 31, 2016·Chemistry : a European Journal·Yannick D BidalCatherine S J Cazin
Oct 26, 2016·Chemistry : a European Journal·Alexander M PolgarJohn F Corrigan
Apr 5, 2017·Angewandte Chemie·Mohand MelaimiGuy Bertrand
Apr 11, 2017·Chemical Reviews·Claudia CoughlanKevin M Ryan
Jul 27, 2017·Chemical Communications : Chem Comm·Rasha HamzeMark E Thompson
Sep 28, 2017·Journal of the American Chemical Society·Alexander M PolgarJohn F Corrigan
Jan 16, 2018·Chemical Communications : Chem Comm·Sharareh Bagherzadeh, Neal P Mankad

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