Two-dimensional MOF and COF nanosheets: synthesis and applications in electrochemistry

Chemistry : a European Journal
Huan PangYu Xia Xu

Abstract

Metal organic framework (MOF) and covalent organic framework (COF) nanosheets are a new type of two-dimensional (2D) materials with unique design principles and various synthesis methods. It is considered an ideal electrochemical device due to the ultrathin thickness, easily tunable molecular structure, large porosity and other unique properties. There are two common methods to synthesize 2D MOF/COF nanosheets: bottom-up and top-down. The top-down strategy mainly includes ultrasonic assisted exfoliation , electrochemical exfoliation and mechanical exfoliation. Another strategy mainly includes interface synthesis, modulation synthesis, surfactant-assisted synthesis. In this review, the development of ultrathin 2D nanosheets in the field of electrochemistry ( supercapacitors, batteries, oxygen reduction, and hydrogen evolution) is introduced, and highlight their unique dimensional advantages.

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Citations

Feb 24, 2021·Chemistry, an Asian Journal·Zhong-Yu RuanYong-Cong Ou
Feb 25, 2021·Research : a Science Partner Journal·Jie ZhengXian Jun Loh
Apr 29, 2021·Journal of Materials Chemistry. B, Materials for Biology and Medicine·Cristian ValenzuelaJianhua Zhang
Jul 22, 2021·Chemistry : a European Journal·Ravinder KumarShaikh M Mobin
Jun 2, 2020·Journal of the American Chemical Society·Allison Claire HinckleyZhenan Bao
Sep 26, 2021·Angewandte Chemie·Bo YangZhan-Ting Li

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