Two-dimensional stimulated resonance Raman spectroscopy of molecules with broadband x-ray pulses.

The Journal of Chemical Physics
Jason D BiggsShaul Mukamel

Abstract

Expressions for the two-dimensional stimulated x-ray Raman spectroscopy (2D-SXRS) signal obtained using attosecond x-ray pulses are derived. The 1D- and 2D-SXRS signals are calculated for trans-N-methyl acetamide (NMA) with broad bandwidth (181 as, 14.2 eV FWHM) pulses tuned to the oxygen and nitrogen K-edges. Crosspeaks in 2D signals reveal electronic Franck-Condon overlaps between valence orbitals and relaxed orbitals in the presence of the core-hole.

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Citations

Oct 5, 2013·The Journal of Chemical Physics·Konstantin E DorfmanShaul Mukamel
Apr 14, 2013·The Journal of Chemical Physics·Yu ZhangShaul Mukamel
Apr 14, 2013·The Journal of Chemical Physics·Jason D BiggsShaul Mukamel
Dec 19, 2012·Annual Review of Physical Chemistry·Shaul MukamelJason D Biggs
Jan 17, 2015·The Journal of Chemical Physics·Bijay Kumar AgarwallaShaul Mukamel
Jan 1, 2014·Structural Dynamics·Daniel HealionShaul Mukamel
Jan 3, 2015·The Journal of Chemical Physics·Nanna Holmgaard ListOve Christiansen
May 10, 2016·The Journal of Physical Chemistry Letters·Tobias FahlesonPatrick Norman
Jun 28, 2016·Journal of Chemical Theory and Computation·Jérémy R RouxelShaul Mukamel
Aug 26, 2016·Proceedings of the National Academy of Sciences of the United States of America·Konstantin E DorfmanShaul Mukamel
Feb 6, 2017·The Journal of Physical Chemistry Letters·Sven KarstenOliver Kühn
Aug 24, 2013·Nature·M BeyeA Föhlisch
Apr 16, 2015·Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry·Yu ZhangShaul Mukamel
Oct 15, 2013·Physical Review Letters·A MarinelliC Pellegrini
Apr 25, 2015·Physical Review Letters·S Miyabe, P Bucksbaum
Jan 28, 2014·Physical Review. a·Konstantin E DorfmanShaul Mukamel
Jun 30, 2018·Physical Review Letters·Jérémy R RouxelShaul Mukamel
Oct 11, 2017·Chemical Science·Yu ZhangShaul Mukamel
Feb 19, 2019·Chemical Science·Jérémy R RouxelShaul Mukamel
Feb 1, 2019·Optics Letters·C SvetinaP Beaud
Apr 18, 2020·Proceedings of the National Academy of Sciences of the United States of America·Shicheng Jiang, Konstantin Dorfman
Jan 25, 2013·Physical Review Letters·Victor Kimberg, Nina Rohringer
Feb 20, 2021·Physical Review Letters·Bing GuShaul Mukamel
Jul 26, 2014·Physical Review Letters·G MarcusA A Zholents
Apr 16, 2013·Physical Review Letters·A A LutmanH-D Nuhn
Mar 31, 2021·Physical Review Letters·Joseph P DurisAgostino Marinelli
Jun 23, 2021·The Journal of Physical Chemistry Letters·Stefano M CavalettoShaul Mukamel
Jul 10, 2021·The Journal of Chemical Physics·Adam E A Fouda, Phay J Ho
Jun 5, 2018·The Journal of Physical Chemistry Letters·Jeremy R RouxelShaul Mukamel
Jun 12, 2013·The Journal of Physical Chemistry Letters·Daniel HealionShaul Mukamel
Jan 1, 2014·Journal of Chemical Theory and Computation·Weijie HuaShaul Mukamel

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Methods Mentioned

BETA
x-ray spectroscopy
x-ray Raman spectroscopy
x-ray scattering
x-ray Raman
X-ray

Software Mentioned

GAUSSIAN
PSI3

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