Ultrafast charge transfer excited state dynamics in trifluoromethyl-substituted iridium(iii) complexes

Physical Chemistry Chemical Physics : PCCP
Robin BevernaegieBenjamin Elias

Abstract

Time-resolved spectroscopy was exploited to gain new insights into the nature and dynamics of charge transfer excited states of bis-cyclometalated Ir(iii) complexes. We showed that its dynamics is strongly influenced by the nature of the diimine ligand due to the existence of a ligand-ligand charge transfer process in the picosecond timescale. All the results are supported by DFT/TD-DFT calculations and spectroelectrochemistry.

References

Jul 28, 2004·Chemical Communications : Chem Comm·Paolo CoppoLuisa De Cola
Jul 26, 2011·Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry·Arthur R G SmithBen J Powell
Aug 14, 2012·Angewandte Chemie·Rubén D CostaNicola Armaroli
Mar 9, 2013·Inorganic Chemistry·M Teresa IndelliRaymond Ziessel
Mar 24, 2016·Physical Chemistry Chemical Physics : PCCP·Stefanie TschierleiStefan Lochbrunner
Nov 1, 2016·Journal of Fluorescence·Quentin DeraedtBenjamin Elias
May 17, 2017·Inorganic Chemistry·Cédric LentzBenjamin Elias
Jun 7, 2018·The Journal of Physical Chemistry. a·Xiang-Yang LiuGanglong Cui

❮ Previous
Next ❯

Citations

Aug 20, 2020·Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry·Jeongwook HwangKyung-Ryang Wee
Aug 12, 2021·Journal of the American Chemical Society·Hannah SayreRobert R Knowles
Oct 24, 2019·Journal of the American Chemical Society·Robin BevernaegieBenjamin Elias
Mar 5, 2020·Journal of the American Chemical Society·Bin XuUttam K Tambar
Jan 25, 2020·Inorganic Chemistry·Justin WeynandBenjamin Elias
Jan 16, 2020·Journal of the American Chemical Society·Robin BevernaegieLudovic Troian-Gautier

❮ Previous
Next ❯

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.

Related Papers

Tanpakushitsu kakusan koso. Protein, nucleic acid, enzyme
F Tanaka, N Mataga
Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry
Nigel D BrowningBryan W Reed
© 2022 Meta ULC. All rights reserved