Ultrathin nanosheets of Li2MSiO4 (M = Fe, Mn) as high-capacity Li-ion battery electrode

Nano Letters
Dinesh RangappaItaru Honma

Abstract

Novel ultrathin Li(2)MnSiO(4) nanosheets have been prepared in a rapid one pot supercritical fluid synthesis method. Nanosheets structured cathode material exhibits a discharge capacity of ~340 mAh/g at 45 ± 5 °C. This result shows two lithium extraction/insertion performances with good cycle ability without any structural instability up to 20 cycles. The two-dimensional nanosheets structure enables us to overcome structural instability problem in the lithium metal silicate based cathode materials and allows successful insertion/extraction of two complete lithium ions.

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Citations

Mar 7, 2013·ACS Applied Materials & Interfaces·Xiaozhen WuYouxiang Zhang
May 30, 2013·ACS Nano·Xianhong RuiQingyu Yan
Jun 20, 2015·Scientific Reports·Murukanahally Kempaiah DevarajuItaru Honma
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