Unraveling the mechanism of molecular doping in organic semiconductors

Advanced Materials
Alexander MityashinPaul Heremans

Abstract

The mechanism by which molecular dopants donate free charge carriers to the host organic semiconductor is investigated and is found to be quite different from the one in inorganic semiconductors. In organics, a strong correlation between the doping concentration and its charge donation efficiency is demonstrated. Moreover, there is a threshold doping level below which doping simply has no electrical effect.

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