Unraveling the mechanism of the singlet oxygen ene reaction: recent computational and experimental approaches

Chemistry : a European Journal
Mariza N Alberti, Michael Orfanopoulos

Abstract

The mechanism of the singlet oxygen ene reaction has been a subject of renewed interest within the last few years. The main question being whether this reaction proceeds through a concerted mechanism or if it involves discrete intermediates. In general, the majority of experimental and computational studies support a traditional stepwise mechanism involving a perepoxide-like intermediate. In this minireview we highlight the most prominent and recent theoretical, as well as experimental results relating to the challenging mechanism of the singlet oxygen ene oxyfunctionalization.

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Citations

Oct 17, 2015·Journal of the American Chemical Society·Matthias Klaper, Torsten Linker
Jan 18, 2018·Chemistry : a European Journal·Audrey MaugerVincent Coeffard
Jun 11, 2019·Chemical Communications : Chem Comm·Louis PéaultVincent Coeffard
Jul 18, 2012·Organic & Biomolecular Chemistry·Lynsey J WatsonMichael J Hall
Mar 4, 2011·Angewandte Chemie·Gregor Meier, Thomas Braun
May 23, 2019·Journal of Immunoassay & Immunochemistry·Rizwan Ahmad, Haseeb Ahsan
Sep 16, 2020·Free Radical Biology & Medicine·Aditya KumarPavel Pospíšil
Jan 29, 2021·Water Science and Technology : a Journal of the International Association on Water Pollution Research·Xuecheng SunShuguang Lyu
Nov 4, 2020·Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry·Adrian MéndezJaime Escalante
Sep 5, 2020·The Journal of Organic Chemistry·Shakeela JabeenAlexander Greer
Apr 4, 2021·Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry·Jayson S WauMichael Oelgemöller
Feb 14, 2012·The Journal of Organic Chemistry·Ramanan Rajeev, Raghavan B Sunoj
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Oct 8, 2021·Photochemical & Photobiological Sciences : Official Journal of the European Photochemistry Association and the European Society for Photobiology·Marco CortiPaolo Quadrelli

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