Using Hydrazine to Link Ferrocene with Re(CO)3: A Modular Approach

Journal of Organometallic Chemistry
Kullapa ChanawannoChristopher J Ziegler

Abstract

Acetyl ferrocene and diacetyl ferrocene both readily react with an excess of hydrazine to afford the corresponding hydrazone compounds. These compounds can then be linked to Re(CO)3 via a metal-mediated Schiff base reaction, resulting in a series of ferrocene-Re(CO)3 conjugates with different stoichiometries. Conjugates with 1:1, 1:2, and 2:1 ferrocene: Re(CO)3 ratios can be produced via this "modular" type synthesis approach. Several examples of these conjugates were structurally characterized, and their spectroscopic, electrochemical, and spectroelectrochemical behaviors were investigated. The electronic structures of these compounds were also probed using DFT and TDDFT calculations.

Citations

Aug 20, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Kullapa ChanawannoChristopher J Ziegler
Apr 23, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Chilaluck C KonkankitJustin J Wilson

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