Viologen-Based Rotaxanes from Dibenzo-30-crown-10

Journal of the American Chemical Society
Hanlie R WesselsHarry W Gibson

Abstract

Three [2]rotaxanes (4, 7, and 12) and one [3]rotaxane (8) were synthesized based on the dibenzo-30-crown-10/viologen binding motif. To the best of our knowledge, these are the first rotaxanes formed from dibenzo-30-crown-10 and viologens. The rotaxanes were all characterized by 1H NMR, 13C NMR, and HRMS. An X-ray crystal structure of one of the [2]rotaxanes (7) was obtained. This work demonstrates for the first time that dibenzo-30-crown-10 does form pseudorotaxane complexes with viologens in solution.

References

May 29, 2000·Organic Letters·W S BryantH W Gibson
Mar 20, 2003·Journal of the American Chemical Society·Harry W GibsonJason W Jones
Apr 13, 2005·The Journal of Organic Chemistry·Feihe HuangHarry W Gibson
Jun 29, 2005·Chemical Communications : Chem Comm·Feihe HuangHarry W Gibson
Jul 31, 2008·Chemical Communications : Chem Comm·Nicolas ChristinatKay Severin
Apr 20, 2011·Chemical Communications : Chem Comm·Natalie D SuhanStephen J Loeb
Oct 21, 2011·Chemical Society Reviews·Bo ZhengFeihe Huang
Jun 2, 2012·Angewandte Chemie·Mingming ZhangFeihe Huang
Jul 10, 2012·Chemical Society Reviews·Shao-Lu LiLeyong Wang
Oct 20, 2012·Angewandte Chemie·Guangyan DuNicolas Giuseppone
Dec 25, 2012·Journal of the American Chemical Society·Xiaofan JiFeihe Huang
Jan 12, 2013·Science·Bartosz LewandowskiDavid A Leigh
Mar 21, 2013·Nature Chemistry·Paul R McGonigal, J Fraser Stoddart
Sep 11, 2013·Advanced Materials·Chuancheng JiaXuefeng Guo
Oct 16, 2013·Chemistry : a European Journal·Joshua LehrPaul D Beer
Jun 1, 2014·Accounts of Chemical Research·Carson J Bruns, J Fraser Stoddart
Aug 5, 2014·Chemical Communications : Chem Comm·Lipeng HeWeifeng Bu
May 13, 2015·Chemical Society Reviews·Victor BlancoVanesa Marcos
Jun 11, 2015·Journal of the American Chemical Society·Steven HoekmanDiederik Roke
Apr 3, 2016·Chemistry : a European Journal·Stephanie ValentinaToshikazu Takata
Jun 1, 1991·Journal of the American Chemical Society·Pier Lucio AnelliJ Fraser Stoddart
Feb 16, 2017·ACS Medicinal Chemistry Letters·David B SmithrudPheruza Tarapore
Jul 18, 2017·The Journal of Organic Chemistry·Terry L PriceHarry W Gibson
Sep 12, 2017·Accounts of Chemical Research·Diana DöhlerWolfgang H Binder
Oct 21, 2017·Science·Sundus Erbas-CakmakMiriam R Wilson
Dec 23, 2017·The Journal of Organic Chemistry·Jason W JonesHarry W Gibson
Mar 7, 2018·Journal of the American Chemical Society·Terry L Price, Harry W Gibson
Sep 18, 1998·Angewandte Chemie·Nori YamaguchiHarry W Gibson

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Citations

Jan 25, 2020·Science Advances·Chi ZhangHao Li
Aug 26, 2021·Chemistry : a European Journal·Marianna MarchiniPaola Ceroni

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