Visible Light Induced Organic Transformations Using Metal-Organic-Frameworks (MOFs)

Chemistry : a European Journal
Xiaoyu DengHermenegildo García

Abstract

With the aim of developing renewable energy based processes, researchers are paying increasing interest to light induced organic transformations. Metal-organic frameworks (MOFs), a class of micro-/mesoporous hybrid materials, are recently emerging as a new type of photoactive materials for organic syntheses due to their unique structural characteristics. In this Review, we summarized the recent applications of MOFs as photocatalysts for light induced organic transformations, including (1) oxidation of alcohols, amines, alkene, alkanes and sulfides; (2) hydroxylation of aromatic compounds like benzene; (3) activation of the C-H bonds to construct new C-C or C-X bonds; (4) atom-transfer radical polymerization (ATRP). This Review starts with general background information of using MOFs in photocatalysis, followed by a description of light induced organic transformations promoted by photoactive inorganic nodes and photocatalytic active ligands in MOFs, respectively. Thereafter, the use of MOFs as multifunctional catalysts for light induced organic transformations via an efficient merge of the metal/ligand/guest based catalysis where the photocatalytic activity of MOFs plays a key role are discussed. Finally, the limitations, challe...Continue Reading

References

Oct 19, 2004·Chemical Communications : Chem Comm·S BordigaA Zecchina
Mar 27, 2007·Chemistry : a European Journal·Mercedes AlvaroHermenegildo Garcia
Jul 5, 2007·Chemical Communications : Chem Comm·Patricia HorcajadaGérard Férey
Sep 27, 2008·Journal of the American Chemical Society·Jasmina Hafizovic CavkaKarl Petter Lillerud
Apr 23, 2009·Chemical Society Reviews·Zhenqiang Wang, Seth M Cohen
Apr 23, 2009·Chemical Society Reviews·JeongYong LeeJoseph T Hupp
Jul 23, 2009·Journal of the American Chemical Society·Meenakshi Dan-HardiGérard Férey
Aug 1, 2009·Journal of the American Chemical Society·Xiufang ChenXinchen Wang
Aug 20, 2009·Angewandte Chemie·David FarrussengCatherine Pinel
Oct 13, 2009·Journal of the American Chemical Society·Attila J MozerDavid L Officer
Jan 15, 2010·Journal of the American Chemical Society·Allison G CondieCorey R J Stephenson
Apr 3, 2010·Chemical Reviews·A CormaF X Llabrés i Xamena
Jun 10, 2010·Chemical Society Reviews·Jagan M R Narayanam, Corey R J Stephenson
Aug 6, 2010·Chemistry : a European Journal·Cláudia Gomes SilvaHermenegildo García
Sep 21, 2010·Journal of the American Chemical Society·Eric D BlochOmar M Yaghi
Sep 21, 2010·Chemical Society Reviews·Chuncheng ChenJincai Zhao
Nov 11, 2010·Chemical Reviews·Xiaobo ChenSamuel S Mao
Jan 20, 2011·Angewandte Chemie·Thorsten Bach, Jörg P Hehn
Feb 4, 2011·Chemical Communications : Chem Comm·Hai-Long Jiang, Qiang Xu
Jul 26, 2011·Journal of the American Chemical Society·Cheng WangWenbin Lin
Sep 6, 2011·Journal of the American Chemical Society·Shane ArdoGerald J Meyer
Oct 6, 2011·Advanced Materials·Hua TongJinhua Ye
Oct 8, 2011·Chemical Reviews·Jian-Rong LiHong-Cai Zhou
Oct 20, 2011·Chemical Society Reviews·Weimin XuanYong Cui
Oct 29, 2011·Journal of the American Chemical Society·Shishi LinTehshik P Yoon
Nov 11, 2011·Chemical Reviews·Lauren E KrenoJoseph T Hupp
Nov 16, 2011·Current Gastroenterology Reports·Karl Heinz Weiss, Wolfgang Stremmel
Dec 16, 2011·Chemical Reviews·Patricia HorcajadaChristian Serre
Dec 24, 2011·Chemical Reviews·Myunghyun Paik SuhDae-Woon Lim
Jan 28, 2012·Chemical Reviews·Hong-Cai ZhouOmar M Yaghi
Jun 15, 2012·Angewandte Chemie·Alexandra FateevaMatthew J Rosseinsky
Aug 15, 2012·Journal of the American Chemical Society·Pengyan WuChunying Duan
Nov 30, 2012·Chemical Society Reviews·Hoi Ri MoonMyunghyun Paik Suh
Jan 9, 2013·Journal of the American Chemical Society·Shengye JinJoseph T Hupp
Mar 28, 2013·Accounts of Chemical Research·Jinhui YangCan Li
Jul 12, 2013·Journal of the American Chemical Society·Christopher H HendonAron Walsh

❮ Previous
Next ❯

Citations

Sep 25, 2017·Chemical Communications : Chem Comm·Amarajothi DhakshinamoorthyHermenegildo Garcia
Jun 7, 2018·Angewandte Chemie·Javier Castells-GilCarlos Martí-Gastaldo
Jul 14, 2018·Chemical Society Reviews·Amarajothi DhakshinamoorthyHermenegildo Garcia
Aug 15, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Cong-Cong ShenAn-Wu Xu
Jul 18, 2018·Chemistry : a European Journal·Ruoyu XuWenbin Lin
Aug 2, 2018·Angewandte Chemie·Aleksandr SavateevMarkus Antonietti
Nov 15, 2018·Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry·Shu-Na ZhaoPascal Van Der Voort
Nov 23, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Andrea Santiago-PortilloHermenegildo García
Jan 10, 2018·Chemistry : a European Journal·Pengfei YangJinlou Gu
May 22, 2020·Physical Chemistry Chemical Physics : PCCP·Xiaolang ChenHiromi Yamashita
Nov 21, 2020·ChemPlusChem·Stefano Mazzanti, Aleksandr Savateev
Jul 10, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Nejat Redwan HabibIsabel Diaz
Sep 11, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Yuhuan QinZhaohui Li

❮ Previous
Next ❯

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.