Visible light photooxidation of nitrate: the dawn of a nocturnal radical

Chemical Communications : Chem Comm
Thea HeringBurkhard König

Abstract

Highly oxidizing nitrate radicals (NO3˙) are easily accessed from readily available nitrate salts by visible light photoredox catalysis using a purely organic dye as the catalyst and oxygen as the terminal oxidant. The interaction of the excited catalyst and nitrate anions was studied by spectroscopic methods to elucidate the mechanism, and the method was applied to the NO3˙ induced oxidation of alkynes and alcohols.

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Citations

Jun 11, 2016·Chemical Reviews·Nathan A Romero, David A Nicewicz
Jun 30, 2016·The Journal of Organic Chemistry·Thea HeringBurkhard König
Aug 6, 2015·Organic & Biomolecular Chemistry·Ricardo A AngnesGerald B Hammond
Aug 18, 2016·Chemical Communications : Chem Comm·Andreas Uwe MeyerBurkhard König
Aug 2, 2017·Chemical Communications : Chem Comm·Vjekoslav Štrukil, Igor Sajko
Jul 17, 2019·Chemical Communications : Chem Comm·Jie ZhouHua-Jian Xu
Jan 11, 2020·Chemistry : a European Journal·Sk Sheriff ShahN D Pradeep Singh
Jun 15, 2019·Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry·Rik H Verschueren, Wim M De Borggraeve
Oct 2, 2020·Angewandte Chemie·Matthias SchmalzbauerBurkhard König
Mar 26, 2021·The Journal of Organic Chemistry·Duyi ShenMianran Chao
May 20, 2021·Organic & Biomolecular Chemistry·M Victoria BoboAaron K Vannucci
May 28, 2020·Journal of the American Chemical Society·Joshua B McManusDavid A Nicewicz
Aug 14, 2019·The Journal of Organic Chemistry·Wen YangDingqiao Yang

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