Water stabilization of Zr6 -based metal-organic frameworks via solvent-assisted ligand incorporation

Chemical Science
Pravas DeriaOmar K Farha

Abstract

Water stability in metal-organic frameworks (MOFs) is critical for several practical applications. While water instability is mainly thought to stem from linker hydrolysis, MOFs with strong, hydrolysis-resistant metal-linker bonds can be susceptible to damage by capillary forces, which cause cavities and channels to collapse during activation from water. This study utilizes metal node functionalization as a strategy to create vapor-stable and recyclable MOFs.

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Citations

Feb 3, 2016·Chemical Communications : Chem Comm·Su-Young MoonOmar K Farha
Jul 14, 2016·Chemical Society Reviews·Chenghong WangKang Li
Aug 1, 2016·Chemical Science·Martino RimoldiOmar K Farha
Dec 24, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Jing-Wen SunGuang-Ming Li
Sep 30, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Xinlin LiPravas Deria
Mar 25, 2020·Chemical Science·Meili DingHai-Long Jiang
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Sep 22, 2015·Journal of the American Chemical Society·Pravas DeriaOmar K Farha
May 16, 2020·Chemical Reviews·Xinlei LiuFreek Kapteijn

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Methods Mentioned

BETA
X-ray

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