Well-defined, organic nanoenvironments in water: the hydrophobic effect drives a capsular assembly

Journal of the American Chemical Society
Corinne L D Gibb, Bruce C Gibb

Abstract

The synthesis of a water-soluble, deep-cavity cavitand is reported. A blend of molecular curvature and amphiphilicity, this molecule has a hydrophobic concave surface and a hydrophilic convex surface. As a result, in aqueous solution and in the presence of a guest molecule, the host self-assembles to form a capsular assembly with an interior cavity large enough to entrap steroidal guests.

References

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Citations

Nov 13, 2013·Journal of Computer-aided Molecular Design·Corinne L D Gibb, Bruce C Gibb
Aug 25, 2011·Accounts of Chemical Research·Laren M TolbertKyril M Solntsev
Mar 2, 2012·Inorganic Chemistry·Peter D FrischmannMark J MacLachlan
Sep 8, 2010·Journal of the American Chemical Society·Shuichi HiraokaMitsuhiko Shionoya
Dec 23, 2010·Journal of the American Chemical Society·Anthony BaldridgeLaren M Tolbert
Sep 14, 2011·Journal of the American Chemical Society·Masamichi YamanakaKenji Kobayashi
Mar 16, 2012·Journal of the American Chemical Society·Hao TangCornelia Bohne
Aug 31, 2012·Journal of the American Chemical Society·Mintu PorelVaidhyanathan Ramamurthy
Mar 2, 2013·Journal of the American Chemical Society·Simin LiuBruce C Gibb
Apr 30, 2013·Journal of the American Chemical Society·Yoo-Jin GhangRichard J Hooley
Oct 18, 2013·Journal of the American Chemical Society·Qi Zhang, Konrad Tiefenbacher
Nov 20, 2013·Journal of the American Chemical Society·Kang-Da ZhangJulius Rebek
Dec 17, 2009·Journal of the American Chemical Society·Naoki NishimuraKenji Kobayashi
Jan 21, 2010·Journal of the American Chemical Society·Anthony BaldridgeLaren M Tolbert
Apr 25, 2012·The Journal of Organic Chemistry·Yanhua QiuAngel E Kaifer
Jul 14, 2011·Langmuir : the ACS Journal of Surfaces and Colloids·Mintu PorelV Ramamurthy
Oct 21, 2005·Organic Letters·Amanda J GallantMark J MacLachlan
Dec 27, 2011·Organic Letters·José P Da SilvaV Ramamurthy
Jan 26, 2012·Organic Letters·Katherine E DjernesRichard J Hooley
Mar 5, 2013·Organic Letters·Pradeepkumar JagadesanV Ramamurthy
Aug 29, 2013·Organic Letters·Nithyanandhan JayarajV Ramamurthy
Jun 5, 2007·Nature Protocols·Xuejun Liu, Ralf Warmuth
May 29, 2007·Chemical Communications : Chem Comm·Corinne L D Gibb, Bruce C Gibb
Mar 14, 2008·Chemical Communications : Chem Comm·Onome UgonoK Travis Holman
May 14, 2008·Chemical Communications : Chem Comm·Anthony W ColemanJohn A Ripmeester
May 26, 2009·Dalton Transactions : an International Journal of Inorganic Chemistry·Markus TonigoldDirk Volkmer
Sep 26, 2008·Chemical Communications : Chem Comm·Kannupal Srinivasan, Bruce C Gibb
Dec 3, 2008·Chemical Communications : Chem Comm·Richard J HooleyJulius Rebek
May 15, 2009·Dalton Transactions : an International Journal of Inorganic Chemistry·Arun Kumar SundaresanV Ramamurthy
Oct 14, 2010·Chemical Communications : Chem Comm·Agustí Lledó, Julius Rebek
Feb 18, 2011·Chemical Communications : Chem Comm·Simin Liu, Bruce C Gibb
May 24, 2011·Chemical Communications : Chem Comm·Yejia LiScott M Grayson
Apr 28, 2011·Photochemical & Photobiological Sciences : Official Journal of the European Photochemistry Association and the European Society for Photobiology·Anand Parthasarathy, V Ramamurthy
Jan 21, 2012·Physical Chemistry Chemical Physics : PCCP·Piyush P WanjariHenry S Ashbaugh
Jun 26, 2012·Photochemical & Photobiological Sciences : Official Journal of the European Photochemistry Association and the European Society for Photobiology·S R SamantaV Ramamurthy
Jun 15, 2011·Supramolecular Chemistry·Simin LiuBruce C Gibb
Jun 27, 2009·Science·Prasenjit MalJonathan R Nitschke
Jan 11, 2014·Chemical Communications : Chem Comm·N Kodiah BeyehKari Rissanen
Dec 24, 2013·The Journal of Chemical Physics·Piyush P WanjariHenry S Ashbaugh
Mar 7, 2014·Journal of Computer-aided Molecular Design·Hari S MuddanaMichael K Gilson

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