X-ray structure analysis of symmetrically substituted 1,1'-diformyl-ruthenocene

Acta Crystallographica. Section E, Crystallographic Communications
Bertin AnzaldoRené Gutiérrez Pérez

Abstract

1,1'-Di-formyl-ruthenocene, [Ru(C6H5O)2], crystallizes in the ortho-rhom-bic system in the P212121 space group at room temperature. There are two crystallographically independent mol-ecules in the asymmetric unit. The cyclo-penta-dienyl rings have eclipsed configuration. The mol-ecules self-assemble in a two-dimensional structure by C-H⋯O and C-H⋯π inter-actions with cisoid relative orientations of the two formyl groups. The crystal studied was refined as an inversion twin.

Methods Mentioned

BETA
X-ray

Software Mentioned

SPARTAN16

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