Zinc(II) and Copper(II) Hybrid Frameworks via Metal-Ion Metathesis with Enhanced Gas Uptake and Photoluminescence Properties

Inorganic Chemistry
Pei-Pei CuiWei-Yin Sun

Abstract

The fabrication of metal-organic frameworks with controlled structure and desired properties is important but still a challenge. In this work, a zinc(II) framework, {[Zn3(L)2(DABCO)(H2O)]·9DMF} (named as Zn-1), has been synthesized based on [1,1':3',1″-terphenyl]-4,4″,5'-tricarboxylic acid (H3L) and 1,4-diazabicyclo[2.2.2]octane (DABCO), which is isostructural to the previously reported copper(II) analogue, {[Cu3(L)2(DABCO)(H2O)]·15H2O·9DMF} (named as Cu-1). Interestingly, hybrid zinc(II) and copper(II) bimetallic frameworks have been obtained via metal-ion metathesis and found to show enhanced adsorption and photoluminescence properties. Such a post-metal-ion metathesis method can be used to synthesize new and desired frameworks that could not be obtained by direct synthesis.

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Citations

Jan 16, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Li-Wei LeeKuang-Lieh Lu
Feb 9, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Pedro J Llabrés-CampanerRafael Ballesteros-Garrido
Mar 13, 2020·Chemical Communications : Chem Comm·Yi LiuWei-Yin Sun
Aug 12, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Richa RajakShaikh M Mobin

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