Zinc(II) mediated imine-enamine tautomerization

Organic Letters
Prem N BasaAndrew G Sykes

Abstract

Reduction of imine-anthracenone compounds selectively produces secondary alcohols leaving the external imine group unreacted. Addition of the Zn(II) ion induces a metal-mediated imine-enamine tautomerization reaction that is selective for Zn(II), a new fluorescence detection method not previously observed for this important cation.

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Aug 24, 2011·The Journal of Organic Chemistry·Prem N BasaAndrew G Sykes
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Citations

Feb 28, 2015·Journal of Fluorescence·Xuhua TianYu Zhang
Feb 18, 2020·Chemical Communications : Chem Comm·Roberto CostantiniAlbano Cossaro
Aug 29, 2012·The Journal of Organic Chemistry·Prem N Basa, Andrew G Sykes

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